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Mendeleev Communications, 2015, Volume 25, Issue 6, Pages 452–453
DOI: https://doi.org/10.1016/j.mencom.2015.11.018
(Mi mendc2442)
 

This article is cited in 8 scientific papers (total in 8 papers)

Communications

Synthesis of S-difluoromethyl dithiocarbamates

V. O. Smirnova, A. S. Maslovab, M. I. Struchkovaa, D. E. Arkhipovc, A. D. Dilmana

a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
c A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
Abstract: A method for preparation of S-difluoromethyl dithiocarbamates has been developed, which involves the treatment of secondary amines with carbon disulfide in methanol followed by S-difluoromethylation of the intermediate dithiocarbamate anion with difluorocarbene generated from (bromodifluoromethyl)trimethylsilane.
Bibliographic databases:
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (843.5 Kb)


Citation: V. O. Smirnov, A. S. Maslov, M. I. Struchkova, D. E. Arkhipov, A. D. Dilman, “Synthesis of S-difluoromethyl dithiocarbamates”, Mendeleev Commun., 25:6 (2015), 452–453
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  • https://www.mathnet.ru/eng/mendc/v25/i6/p452
  • This publication is cited in the following 8 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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