Abstract:
A method for preparation of S-difluoromethyl dithiocarbamates has been developed, which involves the treatment of secondary amines with carbon disulfide in methanol followed by S-difluoromethylation of the intermediate dithiocarbamate anion with difluorocarbene generated from (bromodifluoromethyl)trimethylsilane.
Citation:
V. O. Smirnov, A. S. Maslov, M. I. Struchkova, D. E. Arkhipov, A. D. Dilman, “Synthesis of S-difluoromethyl dithiocarbamates”, Mendeleev Commun., 25:6 (2015), 452–453
Linking options:
https://www.mathnet.ru/eng/mendc2442
https://www.mathnet.ru/eng/mendc/v25/i6/p452
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