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Mendeleev Communications, 2015, Volume 25, Issue 6, Pages 468–469
DOI: https://doi.org/10.1016/j.mencom.2015.11.024
(Mi mendc2448)
 

This article is cited in 28 scientific papers (total in 28 papers)

Communications

Characterization of the electrocatalytic activity of carbon-supported platinum-based catalysts by thermal gravimetric analysis

I. N. Leontyevab, D. V. Leontyevac, A. B. Kuriganovac, Yu. V. Popovb, O. A. Maslovaa, N. V. Glebovad, A. A. Nechitailovd, N. K. Zeleninad, A. A. Tomashovd, L. Henneta, N. V. Smirnovac

a Conditions Extrêmes et Matériaux: Haute Température et Irradiation, Orléans cedex 2, France
b Department of Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation
c Platov South-Russian State Polytechnic University, Novocherkassk, Russian Federation
d Ioffe Institute, St. Petersburg, Russian Federation
Abstract: Investigations of carbon-supported Pt, Pt3Co, and Pt3Ni electrocatalysts using thermal gravimetric analysis (TGA) in combination with electrochemical measurements of the membrane electrode assemblies (MEA) for proton exchange membrane fuel cells have demonstrated that the onset temperature of the carbon support thermal oxidation and apparent activation energy of this reaction decrease in the following orders: Pt(20%)/C > Pt(35%)/C > Pt(46%)/C and Pt3Ni/C > Pt3Co/C > Pt/C, while MEA power density increases. Thus, TGA can be used as a simple and express technique for analysis of the electrocatalytic activity of carbon-supported Pt-based catalysts for proton exchange membrane fuel cells.
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Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (1.1 Mb)


Citation: I. N. Leontyev, D. V. Leontyeva, A. B. Kuriganova, Yu. V. Popov, O. A. Maslova, N. V. Glebova, A. A. Nechitailov, N. K. Zelenina, A. A. Tomashov, L. Hennet, N. V. Smirnova, “Characterization of the electrocatalytic activity of carbon-supported platinum-based catalysts by thermal gravimetric analysis”, Mendeleev Commun., 25:6 (2015), 468–469
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  • This publication is cited in the following 28 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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