Abstract:
The found increase in the extinction coefficients of ion pairs at the low dielectric permittivity of solutions in binary solvents depends on the nature of a nonpolar solvent, and it is related to not only the transformation of solvate-separated ion pairs into contact ones but also the reorientation of ions in the contact ion pairs.
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Document Type:
Article
Language: English
Citation:
M. V. Tolstykh, K. P. Birin, Yu. V. Nelyubina, V. Yu. Kotov, “Reorientation of ions in contact ion pairs as a factor increasing the intensity of outer-sphere charge transfer bands”, Mendeleev Commun., 24:1 (2014), 47–49
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https://www.mathnet.ru/eng/mendc2469
https://www.mathnet.ru/eng/mendc/v24/i1/p47
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