Abstract:
The Arbuzov-type reaction of chlorofullerene C70Cl10 with P(OEt)3 leads to the formation of C70[P(O)(OEt)2]H and C70[P(O)(OEt)2]2H2, whose molecular structures were determined using ESI mass spectrometry in combination with 1D and 2D NMR spectroscopy.
Citation:
E. A. Khakina, A. A. Yurkova, A. V. Novikov, N. P. Piven', A. V. Chernyak, A. S. Peregudov, P. A. Troshin, “Radical reaction of C70Cl10 with P(OEt)3: isolation and characterization of C70[P(O)(OEt)2]nHn (n = 1, 2)”, Mendeleev Commun., 24:4 (2014), 211–213
Linking options:
https://www.mathnet.ru/eng/mendc2526
https://www.mathnet.ru/eng/mendc/v24/i4/p211
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