E. A. Trofimova, A. B. Dobrynin, T. P. Gerasimova, S. A. Katsyuba, O. G. Sinyashin, D. G. Yakhvarov, “Synthesis, X-ray crystal structure and quantum-chemical study of new dinuclear cobalt complex {Co2[mmm-O2P(H)Mes]2(bpy)4}Br2”, Mendeleev Commun., 23:3 (2013), 135

Mendeleev Communications

RUS ENG

JOURNALS PEOPLE ORGANISATIONS CONFERENCES SEMINARS VIDEO LIBRARY PACKAGE AMSBIB

JavaScript is disabled in your browser. Please switch it on to enable full functionality of the website

	General information
	Latest issue
	Archive

	Search papers
	Search references

	RSS
	Latest issue
	Current issues
	Archive issues
	What is RSS

Mendeleev Commun.:
Year:
Volume:
Issue:
Page:
	Find

Personal entry:
Login:
Password:
	Save password
	Enter
	Forgotten password?
	Register

Mendeleev Communications, 2013, Volume 23, Issue 3, Pages 135–136
DOI: https://doi.org/10.1016/j.mencom.2013.05.004 (Mi mendc2638)

This article is cited in 7 scientific papers (total in 7 papers)

Communications

Synthesis, X-ray crystal structure and quantum-chemical study of new dinuclear cobalt complex {Co₂[mmm-O₂P(H)Mes]₂(bpy)₄}Br₂

E. A. Trofimova^a, A. B. Dobrynin^a, T. P. Gerasimova^a, S. A. Katsyuba^a, O. G. Sinyashin^a, D. G. Yakhvarov^ab

^a A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation
^b Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russian Federation

Full-text PDF (320 kB) Citations (7) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2013.05.004

Abstract: The reaction of cobalt dibromide hexahydrate with 2,2’-bipyridine (bpy) and mesitylphosphinic acid MesP(O)(OH)H (Mes = = 2,4,6-trimethylphenyl) under solvothermal synthesis conditions leads to a new dinuclear cobalt(ii) complex {Co₂[µ-O₂P(H)Mes]₂- (bpy)₄}Br₂ formed by two bridging {µ-O2P(H)Mes}– ligands. X-ray crystal structure analysis of the complex displayed that cobalt ions have distorted octahedral coordination and are doubly bridged by two mesitylphosphinato ligands.

Keywords: 2,2'-bipyridine, bridging phosphinate ligands, dinuclear cobalt complexes, X-Ray crystal structure, quantum-chemical study.

Bibliographic databases:

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(473.5 Kb)

Citation: E. A. Trofimova, A. B. Dobrynin, T. P. Gerasimova, S. A. Katsyuba, O. G. Sinyashin, D. G. Yakhvarov, “Synthesis, X-ray crystal structure and quantum-chemical study of new dinuclear cobalt complex {Co₂[mmm-O₂P(H)Mes]₂(bpy)₄}Br₂”, Mendeleev Commun., 23:3 (2013), 135–136

Linking options:

https://www.mathnet.ru/eng/mendc2638

https://www.mathnet.ru/eng/mendc/v23/i3/p135

This publication is cited in the following 7 articles:

Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

Registration to the website

Logotypes