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This article is cited in 12 scientific papers (total in 12 papers)
Unexpected redox reaction of alkali metal diselenophosphinates with elemental iodine
A. V. Artem'eva, S. F. Malyshevaa, B. G. Sukhova, N. A. Belogorlovaa, Yu. V. Gatilovb, V. I. Mamatyukb, N. K. Gusarovaa a A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation
b N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
Abstract:
Redox reaction between alkali metal diselenophosphinates R2P(Se)SeM (M = Na, K) and elemental iodine in a 2:1 molar ratio (1,4-dioxane, room temperature, 2min) gives bis(diorganylselenophosphoryl)selenides [R2P(Se)]2Se and bis(diorganylselenophosphoryl) triselenides [R2P(Se)]2Se3 in 87–90% total yields.
Citation:
A. V. Artem'ev, S. F. Malysheva, B. G. Sukhov, N. A. Belogorlova, Yu. V. Gatilov, V. I. Mamatyuk, N. K. Gusarova, “Unexpected redox reaction of alkali metal diselenophosphinates with elemental iodine”, Mendeleev Commun., 22:1 (2012), 18–20
Linking options:
https://www.mathnet.ru/eng/mendc2722 https://www.mathnet.ru/eng/mendc/v22/i1/p18
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