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This article is cited in 5 scientific papers (total in 5 papers)
Consecutive Reactions of Dialkyl Ethynyl Carbinols with Acetylene in Superbase KOH/DMSO Suspension
E. Yu. Schmidt, I. A. Bidusenko, N. V. Zorina, I. A. Ushakov, A. I. Mikhaleva, L. V. Klyba, B. A. Trofimov
A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation
Abstract:
2-Methylbut-3-yn-2-ol, a tertiary propargylic alcohol, reacts with acetylene under pressure in superbase KOH/DMSO suspension (80°C, 1h) to afford, along with the expected vinyl ether, 2,2,4,4-tetramethyl-5-methylidene-1,3-dioxolane, 2,5-dimethyl-5-(vinyloxy)hex-3-yn-2-ol and (Z)-2-methyl-4-(2-methylbut-3-yn-2-yloxy)but-3-en-2-ol.
Citation:
E. Yu. Schmidt, I. A. Bidusenko, N. V. Zorina, I. A. Ushakov, A. I. Mikhaleva, L. V. Klyba, B. A. Trofimov, “Consecutive Reactions of Dialkyl Ethynyl Carbinols with Acetylene in Superbase KOH/DMSO Suspension”, Mendeleev Commun., 22:3 (2012), 132–133
Linking options:
https://www.mathnet.ru/eng/mendc2764 https://www.mathnet.ru/eng/mendc/v22/i3/p132
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