N. I. Simirskaya, N. V. Ignat'ev, M. Schulte, S. G. Zlotin, “Mannich Synthesis of Acetylenic Amino Alcohols in Aqueous Ionic Liquids”, Mendeleev Commun., 22:6 (2012), 317

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Mendeleev Communications, 2012, Volume 22, Issue 6, Pages 317–319
DOI: https://doi.org/10.1016/j.mencom.2012.11.013 (Mi mendc2834)

This article is cited in 8 scientific papers (total in 8 papers)

Mannich Synthesis of Acetylenic Amino Alcohols in Aqueous Ionic Liquids

N. I. Simirskaya^a, N. V. Ignat'ev^b, M. Schulte^b, S. G. Zlotin^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b Ionic Liquid Research Laboratory, Merck KGaA, Darmstadt, Germany

Full-text PDF (245 kB) Citations (8) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2012.11.013

Abstract: Terminal alkynols react with formaldehyde and secondary amines in aqueous ionic liquid [emim]HSO^–₄ in the presence of Cu(OAc) to afford the corresponding 1-(a-hydroxyalkyl)- or 1-(b-hydroxyalkyl)-2-(aminomethyl)acetylenes in better yields in comparison with the reaction in conventional organic solvents. The catalytic system can be easily recovered and recycled.

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Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(388.5 Kb)

Citation: N. I. Simirskaya, N. V. Ignat'ev, M. Schulte, S. G. Zlotin, “Mannich Synthesis of Acetylenic Amino Alcohols in Aqueous Ionic Liquids”, Mendeleev Commun., 22:6 (2012), 317–319

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https://www.mathnet.ru/eng/mendc2834

https://www.mathnet.ru/eng/mendc/v22/i6/p317

This publication is cited in the following 8 articles:

Citing articles in Google Scholar: Russian citations, English citations
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