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This article is cited in 10 scientific papers (total in 10 papers)
Free-radical addition of phosphine to vinyl ethers: atom-economic synthesis of tris(2-organyloxyethyl)phosphines and their derivatives
N. K. Gusarova, S. I. Verkhoturova, T. I. Kazantseva, V. L. Mikhailenko, S. N. Arbuzova, B. A. Trofimov
A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation
Abstract:
Phosphine, generated from red phosphorus in the system KOH–H2O–toluene, reacts with vinyl ethers under radical initiation (AIBN, dioxane, 78–80°C, atmospheric pressure) to give tris(2-organyloxyethyl)phosphines, which are transformed to the corresponding phosphine chalcogenides (in up to 73% isolated yield) via the reactions with air oxygen, elemental sulfur or selenium.
Citation:
N. K. Gusarova, S. I. Verkhoturova, T. I. Kazantseva, V. L. Mikhailenko, S. N. Arbuzova, B. A. Trofimov, “Free-radical addition of phosphine to vinyl ethers: atom-economic synthesis of tris(2-organyloxyethyl)phosphines and their derivatives”, Mendeleev Commun., 21:1 (2011), 17–18
Linking options:
https://www.mathnet.ru/eng/mendc2850 https://www.mathnet.ru/eng/mendc/v21/i1/p17
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