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Triethylsilyl triflate-promoted skeletal rearrangement of bottrospicatols
S. A. Torosyan, F. A. Gimalova, R. F. Valeev, M. S. Miftakhov
Ufa Institute of Chemistry, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation
Abstract:
Treatment of diastereomeric (1R,5R,6R)- and (1R,5R,6S)-6-hydroxymethyl-2,6-dimethyl-7-oxabicyclo[3.2.1]oct-2-enes with Et3SiOTf leads to scalemic (1R,5R,6R)- and (1R,5R,6S)-6-hydroxy-2,6-dimethyl-8-oxabicyclo[3.3.1]non-2-enes.
Citation:
S. A. Torosyan, F. A. Gimalova, R. F. Valeev, M. S. Miftakhov, “Triethylsilyl triflate-promoted skeletal rearrangement of bottrospicatols”, Mendeleev Commun., 21:3 (2011), 140–141
Linking options:
https://www.mathnet.ru/eng/mendc2893 https://www.mathnet.ru/eng/mendc/v21/i3/p140
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