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Mendeleev Communications, 2011, Volume 21, Issue 3, Pages 157–159
DOI: https://doi.org/10.1016/j.mencom.2011.04.016
(Mi mendc2901)
 

This article is cited in 6 scientific papers (total in 6 papers)

Kinetics of decay of methyl radicals in irradiated dimethylsilanediol and polymethylsiloxanes

L. N. Pankratovaa, E. V. Saenkoa, V. l. Bugaenkob, V. V. Makhlyarchukc

a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
b A.I. Alikhanov Institute for Theoretical and Experimental Physics, National Research Centre 'Kurchatov Institute', Moscow, Russian Federation
c N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
Abstract: As found by EPR spectroscopy, the decay of methyl radicals in the test compounds upon X-ray irradiation at 77K resulted from radical-center transfer rather than radical combination; the rate constants of decay of methyl radicals in polydimethylsiloxane and its structural analog dimethylsilanediol were almost the same.
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Document Type: Article
Language: English


Citation: L. N. Pankratova, E. V. Saenko, V. l. Bugaenko, V. V. Makhlyarchuk, “Kinetics of decay of methyl radicals in irradiated dimethylsilanediol and polymethylsiloxanes”, Mendeleev Commun., 21:3 (2011), 157–159
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  • https://www.mathnet.ru/eng/mendc/v21/i3/p157
  • This publication is cited in the following 6 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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