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Mendeleev Communications, 2011, Volume 21, Issue 4, Pages 204–205
DOI: https://doi.org/10.1016/j.mencom.2011.07.011 (Mi mendc2917) 		 
This article is cited in 6 scientific papers (total in 6 papers)

Carbamide-containing complexes of lanthanides: competition of hydrogen bonding and polyiodide ion formation

L. Yu. Alikberovaa, K. A. Lyssenkob, N. S. Rukka, A. I. Mytarevaa

a M.V. Lomonosov Institute of Fine Chemical Technologies, MIREA - Russian Technological University, Moscow, Russian Federation
b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
Full-text PDF (550 kB) Citations (6)
DOI: https://doi.org/10.1016/j.mencom.2011.07.011
Abstract: The carbamide complexes of lanthanide polyiodoiodates [Tm(ur)7][I3]3·2I2, [Yb(ur)6][I3]3 and [Lu(ur)6][I3]3 [ur is O=C(NH2)2] have been synthesized and structurally characterized. The structure-forming role of the pentaiodide ions taking part in the formation of extended channels 10–12Å in diameter with incorporated hepta(carbamide)thulium cations combined to one another into infinite columns due to H-bonding, or the triiodide ions forming lace-like net with isolated hexa(carbamide)ytterbium(iii) or hexa(carbamide) lutetium(iii) cations located in the net holes has been revealed.
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Document Type: Article
Language: English


Citation: L. Yu. Alikberova, K. A. Lyssenko, N. S. Rukk, A. I. Mytareva, “Carbamide-containing complexes of lanthanides: competition of hydrogen bonding and polyiodide ion formation”, Mendeleev Commun., 21:4 (2011), 204–205
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  • https://www.mathnet.ru/eng/mendc/v21/i4/p204
    • This publication is cited in the following 6 articles:
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