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Mendeleev Communications, 2023, Volume 33, Issue 1, Pages 11–13
DOI: https://doi.org/10.1016/j.mencom.2023.01.003
(Mi mendc292)
 

This article is cited in 9 scientific papers (total in 9 papers)

Communications

Synthesis of substituted furan-3-carboxylates from alkyl 3-bromo-3-nitroacrylates

K. A. Gomonova, V. V. Pelipkoa, I. A. Litvinovb, R. I. Baichurina, S. V. Makarenkoa

a Herzen State Pedagogical University of Russia, St. Petersburg, Russian Federation
b A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation
Abstract: Carbonyl-containing furan-3-carboxylates were obtained by the refluxing of alkyl 3-bromo-3-nitroacrylates and acyclic CH-acids, namely, pentane-2,4-dione and alkyl 3-oxo-butanoates in methanol in the presence of equimolar amounts of potassium acetate. The products can be prepared by the similar processing of 2-nitro-2,3-dihydrofuran-3-carboxy-lates being the intermediates in the total transformation.
Keywords: nitroacrylates, 1-halo-1-nitroethenes, CH-acids, acetylacetone, alkyl acetoacetates, 2,3-dihydrofurancarboxylates, furan-carboxylates, heterocyclization.
Bibliographic databases:
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (4.3 Mb)


Citation: K. A. Gomonov, V. V. Pelipko, I. A. Litvinov, R. I. Baichurin, S. V. Makarenko, “Synthesis of substituted furan-3-carboxylates from alkyl 3-bromo-3-nitroacrylates”, Mendeleev Commun., 33:1 (2023), 11–13
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  • https://www.mathnet.ru/eng/mendc/v33/i1/p11
  • This publication is cited in the following 9 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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