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Mendeleev Communications, 2023, Volume 33, Issue 1, Pages 50–52
DOI: https://doi.org/10.1016/j.mencom.2023.01.015
(Mi mendc304)
 

This article is cited in 4 scientific papers (total in 4 papers)

Communications

Synthesis of new ionic liquids based on (5Z,9Z)-alkadienoic acids and choline

I. I. Islamova, A. V. Yusupovaa, V. A. D'yakonovb, U. M. Dzhemilevb

a Institute of Petrochemistry and Catalysis, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation
b N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
Abstract: Efficient synthesis of ionic liquids based on stereoisomerically pure natural and synthetic higher (5Z,9Z)-alkadienoic acids and choline hydroxide was developed. The key unsaturated carboxylic acids were prepared using the stereoselective cross-cyclomagnesiation reaction of aliphatic and oxygen-containing 1,2-dienes with EtMgBr in the presence of Mg metal and Cp2TiCl2 catalyst.
Keywords: cross-cyclomagnesiation, Grignard reagents, allenes, titanocene dichloride, (5Z, 9Z)-alkadienoic acids, choline, ionic liquids.
Bibliographic databases:
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (766.6 Kb)


Citation: I. I. Islamov, A. V. Yusupova, V. A. D'yakonov, U. M. Dzhemilev, “Synthesis of new ionic liquids based on (5Z,9Z)-alkadienoic acids and choline”, Mendeleev Commun., 33:1 (2023), 50–52
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  • This publication is cited in the following 4 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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