N. A. Veskina, A. Sh. Ibragimova, I. V. Galyautdinov, L. M. Khalilov, V. N. Odinokov, “Transformation of 9α,14α-epoxy-14-deoxy-20-hydroxyecdysone diacetonide into 25-hydroxydachryhainansterone”, Mendeleev Commun., 20:5 (2010), 293

Mendeleev Communications

RUS ENG

JOURNALS PEOPLE ORGANISATIONS CONFERENCES SEMINARS VIDEO LIBRARY PACKAGE AMSBIB

JavaScript is disabled in your browser. Please switch it on to enable full functionality of the website

	General information
	Latest issue
	Archive

	Search papers
	Search references

	RSS
	Latest issue
	Current issues
	Archive issues
	What is RSS

Mendeleev Commun.:
Year:
Volume:
Issue:
Page:
	Find

Personal entry:
Login:
Password:
	Save password
	Enter
	Forgotten password?
	Register

Mendeleev Communications, 2010, Volume 20, Issue 5, Pages 293–295
DOI: https://doi.org/10.1016/j.mencom.2010.09.019 (Mi mendc3071)

This article is cited in 7 scientific papers (total in 7 papers)

Transformation of 9α,14α-epoxy-14-deoxy-20-hydroxyecdysone diacetonide into 25-hydroxydachryhainansterone

N. A. Veskina, A. Sh. Ibragimova, I. V. Galyautdinov, L. M. Khalilov, V. N. Odinokov

Institute of Petrochemistry and Catalysis, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation

Full-text PDF (249 kB) Citations (7) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2010.09.019

Abstract: 9α,14α-Epoxy-14-deoxy-20-hydroxyecdysone diacetonide on treatment with NaBH₄ undergoes reduction of 6-keto group and cleavage of allylic oxetane ring, the 6-keto reduction is accompanied by β→α epimerization of the adjacent HC⁵ centre. Subsequent re-oxidation of the 6-CHOH fragment into ketone with pyridinium chlorochromate and acidic deprotection affords 25-hydroxydachryhainansterone possessing β-HC⁵ configuration due to the re-epimerisation at this centre.

Keywords: ecdysteroids, oxetane cycle, 7,9-dien systeme, 25-hydroxydachryhainansterone.

Bibliographic databases:

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(103.8 Kb)

Citation: N. A. Veskina, A. Sh. Ibragimova, I. V. Galyautdinov, L. M. Khalilov, V. N. Odinokov, “Transformation of 9α,14α-epoxy-14-deoxy-20-hydroxyecdysone diacetonide into 25-hydroxydachryhainansterone”, Mendeleev Commun., 20:5 (2010), 293–295

Linking options:

https://www.mathnet.ru/eng/mendc3071

https://www.mathnet.ru/eng/mendc/v20/i5/p293

This publication is cited in the following 7 articles:

Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

Registration to the website

Logotypes