V. V. Semenov, S. A. Shevelev, “Reactivity of the low-nucleophilic N-dinitromethyl carbanion center in polynitromethylazoles”, Mendeleev Commun., 20:6 (2010), 332

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Mendeleev Communications, 2010, Volume 20, Issue 6, Pages 332–334
DOI: https://doi.org/10.1016/j.mencom.2010.11.010 (Mi mendc3083)

This article is cited in 20 scientific papers (total in 20 papers)

Reactivity of the low-nucleophilic N-dinitromethyl carbanion center in polynitromethylazoles

V. V. Semenov, S. A. Shevelev

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Full-text PDF (451 kB) Citations (20) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2010.11.010

Abstract: Reactivity of N-dinitromethylazoles possessing extremely high CH acidity (pK_a –1.75–0) was investigated in Michael, Henry and alkylation reactions. N-Dinitromethylazole K-salts and hexamethylenetetramine under acidic conditions yield bis-Mannich bases (86–100%) whose secondary amine moiety can be N-nitrated with HNO₃–H₂SO₄ system.

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Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(116.4 Kb)

Citation: V. V. Semenov, S. A. Shevelev, “Reactivity of the low-nucleophilic N-dinitromethyl carbanion center in polynitromethylazoles”, Mendeleev Commun., 20:6 (2010), 332–334

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https://www.mathnet.ru/eng/mendc3083

https://www.mathnet.ru/eng/mendc/v20/i6/p332

This publication is cited in the following 20 articles:

Citing articles in Google Scholar: Russian citations, English citations
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