|
This article is cited in 10 scientific papers (total in 10 papers)
Ozonolysis of verbenone in aprotic solvents
O. S. Kukovinetsa, T. I. Zverevaa, N. N. Kabal'novab, V. G. Kasradzeb, E. V. Salimovab, L. R. Khalitovab, M. I. Abdullina, L. V. Spirikhinb a Department of Chemical Technology, Bashkirian State University, Ufa, Russian Federation
b Ufa Institute of Chemistry, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation
Abstract:
The ozonolysis of verbenone in methylene chloride and acetonitrile at –60 and 0°C proceeds with cleavage of the double bond and neighbouring σ-bond to give (1R,3S)-acetyl-2,2-dimethylcyclobutane carboxylic acid. The mechanism of the reaction has been proposed.
Keywords:
ozonolysis of verbenone, (1R, 3S)-3-acetyl-2,2-dimethylcyclobutane carboxylic acid, mechanism of ozonolysis, aprotonic solvents.
Citation:
O. S. Kukovinets, T. I. Zvereva, N. N. Kabal'nova, V. G. Kasradze, E. V. Salimova, L. R. Khalitova, M. I. Abdullin, L. V. Spirikhin, “Ozonolysis of verbenone in aprotic solvents”, Mendeleev Commun., 19:2 (2009), 106–107
Linking options:
https://www.mathnet.ru/eng/mendc3135 https://www.mathnet.ru/eng/mendc/v19/i2/p106
|
|