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This article is cited in 10 scientific papers (total in 10 papers)
Cyanomethylamines and azidomethylamines: new general methods of the synthesis and transformations
O. G. Nabiev, Z. O. Nabizade, R. G. Kostyanovsky
N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
Abstract:
Simple and efficient methods have been developed to obtain cyanomethylamines and azidomethylamines using reactions of methoxymethylamines with TMSCN and TMSN3, respectively. In the case of dimethylformamide dimethylacetal, only one MeO group was substituted with CN, and an unexpected direction of the subsequent azidation was found. Adducts of azidomethylamines with DMAD were studied, and the base-catalyzed isomerization of symmetric triazoles into non-symmetric ones was revealed.
Citation:
O. G. Nabiev, Z. O. Nabizade, R. G. Kostyanovsky, “Cyanomethylamines and azidomethylamines: new general methods of the synthesis and transformations”, Mendeleev Commun., 19:5 (2009), 281–283
Linking options:
https://www.mathnet.ru/eng/mendc3200 https://www.mathnet.ru/eng/mendc/v19/i5/p281
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