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This article is cited in 3 scientific papers (total in 3 papers)
Absolute configuration of a chiral proton sponge
R. G. Kostyanovskya, A. F. Pozharskiib, Yu. V. Nelyubinac, K. A. Lyssenkoc, G. K. Kadorkinaa, A. V. Degtyarevb, O. G. Nabieva, I. I. Chervina a N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
b Department of Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation
c A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
Abstract:
By the spontaneous resolution of racemic compound 1,8-bis(dimethylamino)-2-(α-hydroxy-α-phenylethyl)naphthalene (±)-1, enantiomer (–)-1 was obtained; its treatment with C5H5N·HBr resulted in the formation of proton sponge (–)-2; the absolute configurations of (R)-(–)-2 and, as a consequence, (R)-(–)-1 were determined by XRD analysis.
Citation:
R. G. Kostyanovsky, A. F. Pozharskii, Yu. V. Nelyubina, K. A. Lyssenko, G. K. Kadorkina, A. V. Degtyarev, O. G. Nabiev, I. I. Chervin, “Absolute configuration of a chiral proton sponge”, Mendeleev Commun., 18:2 (2008), 86–87
Linking options:
https://www.mathnet.ru/eng/mendc3257 https://www.mathnet.ru/eng/mendc/v18/i2/p86
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