N. A. Nedolya, O. A. Tarasova, A. I. Albanov, O. G. Volostnykh, L. Brandsma, B. A. Trofimov, “A new approach to densely functionalised azepines and dihydroazepines”, Mendeleev Commun., 18:3 (2008), 164

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Mendeleev Communications, 2008, Volume 18, Issue 3, Pages 164–166
DOI: https://doi.org/10.1016/j.mencom.2008.05.018 (Mi mendc3284)

This article is cited in 18 scientific papers (total in 18 papers)

A new approach to densely functionalised azepines and dihydroazepines

N. A. Nedolya^a, O. A. Tarasova^a, A. I. Albanov^a, O. G. Volostnykh^a, L. Brandsma^b, B. A. Trofimov^a

^a A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation
^b Department of Organic Chemistry, University of Utrecht, Utrecht, The Netherlands

Full-text PDF (284 kB) Citations (18) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2008.05.018

Abstract: The easy transformation of 2-(1-alkoxyethoxy)-N-(1-methylethylidene)-1-(methylsulfanyl)-1,3-butadien-1-amines (2-aza-1,3,5-trienes) into 3-(1-alkoxyethoxy)-7-methyl-2-(methylsulfanyl)-4,5-dihydro-3H-azepines and 6-(1-alkoxyethoxy)-2-methyl-3H-azepines has been found to proceed under the action of Bu^tOK in THF–DMSO or THF; the mild acidic hydrolysis of 4,5-dihydro-3H-azepines gives hydroxy derivatives.

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Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(101.1 Kb)

Citation: N. A. Nedolya, O. A. Tarasova, A. I. Albanov, O. G. Volostnykh, L. Brandsma, B. A. Trofimov, “A new approach to densely functionalised azepines and dihydroazepines”, Mendeleev Commun., 18:3 (2008), 164–166

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https://www.mathnet.ru/eng/mendc/v18/i3/p164

This publication is cited in the following 18 articles:

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