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Mendeleev Communications, 2008, Volume 18, Issue 4, Pages 188–190
DOI: https://doi.org/10.1016/j.mencom.2008.07.005
(Mi mendc3291)
 

This article is cited in 10 scientific papers (total in 10 papers)

The Povarov reaction of ethyl (18-carbomethoxyabieta-8,11,13-triene-12-imino)glyoxylate with electron-donating dienophiles

A. V. Tarantina, V. A. Glushkova, O. A. Mayorovaa, I. A. Shcherbininab, A. G. Tolstikova

a Institute of Technical Chemistry, Ural Branch of the Russian Academy of Sciences, Perm, Russian Federation
b Department of Chemistry, Perm State National Research University, Perm, Russian Federation
Abstract: Ethyl (18-carbomethoxyabieta-8,11,13-triene-12-imino)glyoxylate undergoes cyclization with ethyl vinyl ether or N-vinylpyrrolidone to 3-ethoxycarbonyl-5-isopropyl-9-methoxycarbonyl-9,12a-dimethyl-7,8,8a,9,10,11,12,12a-octahydronaphtho[1,2-f]-quinoline under BF3·OEt2 catalysis; the corresponding reaction with cyclopentadiene proceeds with moderate diastereoselectivity at −20°C.
Bibliographic databases:
Document Type: Article
Language: English


Citation: A. V. Tarantin, V. A. Glushkov, O. A. Mayorova, I. A. Shcherbinina, A. G. Tolstikov, “The Povarov reaction of ethyl (18-carbomethoxyabieta-8,11,13-triene-12-imino)glyoxylate with electron-donating dienophiles”, Mendeleev Commun., 18:4 (2008), 188–190
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  • https://www.mathnet.ru/eng/mendc/v18/i4/p188
  • This publication is cited in the following 10 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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