|
This article is cited in 2 scientific papers (total in 2 papers)
A new bright chemiluminescent reaction: interaction of acetone with solid potassium peroxymonosulfate in the complex of europium nitrate
D. V. Kazakova, F. E. Safarova, V. P. Kazakova, R. Schmidtb a Ufa Institute of Chemistry, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation
b Institut für Physikalische und Theoretische Chemie, Johann Wolfgang Goethe-Universität Frankfurt, Frankfurt am Main, Germany
Abstract:
The interaction of acetone with a mixture of potassium peroxymonosulfate and europium nitrate hexahydrate powders at 90°C is accompanied by chemiluminescence due to the formation of excited Eu3+; dioxirane is proposed to be a key intermediate responsible for the chemiluminescence observed.
Keywords:
chemiluminescence, lanthanides, dioxiranes, singlet oxygen.
Citation:
D. V. Kazakov, F. E. Safarov, V. P. Kazakov, R. Schmidt, “A new bright chemiluminescent reaction: interaction of acetone with solid potassium peroxymonosulfate in the complex of europium nitrate”, Mendeleev Commun., 18:5 (2008), 249–250
Linking options:
https://www.mathnet.ru/eng/mendc3314 https://www.mathnet.ru/eng/mendc/v18/i5/p249
|
|