H. J. Frohn, V. V. Bardin, “Distinct reactivities of cis- and trans-RFCF=CFBF2 towards XeF2 and the first synthesis of a [trans-RFCF=CFXe]+ salt”, Mendeleev Commun., 17:3 (2007), 137

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Mendeleev Communications, 2007, Volume 17, Issue 3, Pages 137–138
DOI: https://doi.org/10.1016/j.mencom.2007.05.001 (Mi mendc3403)

This article is cited in 4 scientific papers (total in 4 papers)

Distinct reactivities of cis- and trans-R_FCF=CFBF₂ towards XeF₂ and the first synthesis of a [trans-R_FCF=CFXe]⁺ salt

H. J. Frohn^a, V. V. Bardin^b

^a Department of Chemistry, Institute of Inorganic Chemistry, University of Duisburg-Essen, Duisburg, Germany
^b N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Full-text PDF (226 kB) Citations (4)

DOI: https://doi.org/10.1016/j.mencom.2007.05.001

Abstract: The competitive reaction of C₄F₉CF=CFBF₂ (cis : trans = 1.2:1) with XeF₂ demonstrated for the first time a remarkably lower reaction rate of the trans isomer with respect to the cis isomer in the xenodeborylation reaction (formation of the [C₄F₉CF=CFXe]⁺ cation with a cis : trans ratio of 2.5 to 4:1) and allowed us to develop reaction conditions for the syntheses of [trans-C₄F₉CF=CFXe]⁺ salts.

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Document Type: Article

Language: English

Citation: H. J. Frohn, V. V. Bardin, “Distinct reactivities of cis- and trans-R_FCF=CFBF₂ towards XeF₂ and the first synthesis of a [trans-R_FCF=CFXe]⁺ salt”, Mendeleev Commun., 17:3 (2007), 137–138

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