B. A. Trofimov, L. A. Oparina, N. K. Gusarova, M. Ya. Khil'ko, L. N. Parshina, J. Henkelmann, “Superbase-catalysed addition of methanol to propyne and allene: an expedient synthesis of 2-methoxypropene”, Mendeleev Commun., 16:1 (2006), 13

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Mendeleev Communications, 2006, Volume 16, Issue 1, Pages 13–14
DOI: https://doi.org/10.1070/MC2006v016n01ABEH002198 (Mi mendc3496)

This article is cited in 5 scientific papers (total in 5 papers)

Superbase-catalysed addition of methanol to propyne and allene: an expedient synthesis of 2-methoxypropene

B. A. Trofimov^a, L. A. Oparina^a, N. K. Gusarova^a, M. Ya. Khil'ko^a, L. N. Parshina^a, J. Henkelmann^b

^a A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation
^b BASF AG, Ludwigshafen, Germany

Full-text PDF (191 kB) Citations (5)

DOI: https://doi.org/10.1070/MC2006v016n01ABEH002198

Abstract: In the superbase catalytic systems Bu^tOK/NMP, Am^tOCs/NMP and KOH/DMSO, methanol readily adds to propyne and allene at 100–120 °C and atmospheric pressure to afford 2-methoxypropene in 80–97% yield with 75–94% methanol conversion.

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Document Type: Article

Language: English

Citation: B. A. Trofimov, L. A. Oparina, N. K. Gusarova, M. Ya. Khil'ko, L. N. Parshina, J. Henkelmann, “Superbase-catalysed addition of methanol to propyne and allene: an expedient synthesis of 2-methoxypropene”, Mendeleev Commun., 16:1 (2006), 13–14

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https://www.mathnet.ru/eng/mendc/v16/i1/p13

This publication is cited in the following 5 articles:

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