M. H. Königsmann, E. Lork, I. L. Odinets, V. G. Nenajdenko, N. E. Shevchenko, G.-V. Röschenthaler, “α-Pentafluoroethylated amines: a new synthetic approach”, Mendeleev Commun., 16:3 (2006), 141

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Mendeleev Communications, 2006, Volume 16, Issue 3, Pages 141–143
DOI: https://doi.org/10.1070/MC2006v016n03ABEH002348 (Mi mendc3557)

This article is cited in 5 scientific papers (total in 5 papers)

α-Pentafluoroethylated amines: a new synthetic approach

M. H. Königsmann^ab, E. Lork^b, I. L. Odinets^c, V. G. Nenajdenko^d, N. E. Shevchenko^d, G.-V. Röschenthaler^b

^a Laboratorium für Anorganische Chemie, Zürich, Switzerland
^b Institut für Anorganische und Physikalische Chemie, Universität Bremen, Bremen, Germany
^c A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^d Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Full-text PDF (249 kB) Citations (5)

DOI: https://doi.org/10.1070/MC2006v016n03ABEH002348

Abstract: Pentafluoroethyllithium generated from pentafluoroethane and n-butyl lithium added to selected imines, which were activated using BF₃ etherate, furnished α-pentafluoroethylated amines and, unexpectedly, depending on the stoichiometry of the reactants, bis(pentafluoroethyl)fluoro-N-(isopropyl)diisopropyliminium borate, whose molecular structure was confirmed by X-ray diffraction.

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Document Type: Article

Language: English

Citation: M. H. Königsmann, E. Lork, I. L. Odinets, V. G. Nenajdenko, N. E. Shevchenko, G.-V. Röschenthaler, “α-Pentafluoroethylated amines: a new synthetic approach”, Mendeleev Commun., 16:3 (2006), 141–143

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https://www.mathnet.ru/eng/mendc/v16/i3/p141

This publication is cited in the following 5 articles:

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