V. A. Kurmaz, A. B. Ershler, “Acid-catalysed degradation of the organomercury intermediates of pentafluorophenylmercury bromide reduction near a mercury electrode”, Mendeleev Commun., 16:4 (2006), 234

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Mendeleev Communications, 2006, Volume 16, Issue 4, Pages 234–237
DOI: https://doi.org/10.1070/MC2006v016n04ABEH002259 (Mi mendc3602)

This article is cited in 4 scientific papers (total in 4 papers)

Acid-catalysed degradation of the organomercury intermediates of pentafluorophenylmercury bromide reduction near a mercury electrode

V. A. Kurmaz^a, A. B. Ershler^b

^a Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
^b A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russian Federation

Full-text PDF (231 kB) Citations (4)

DOI: https://doi.org/10.1070/MC2006v016n04ABEH002259

Abstract: The acid-catalysed protolysis of intermediates, formed either during one-electron reduction of substituted arylmercury salt (C₆F₅HgBr) or by the adsorption of bis(arylalkynyl)mercury compound [(PhC≡C)₂Hg] on a Hg electrode has been found in lowacidic media (3 < pH < 6), whereas it was not observed in alkylmercury salt (PrⁿHgOAc).

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Document Type: Article

Language: English

Citation: V. A. Kurmaz, A. B. Ershler, “Acid-catalysed degradation of the organomercury intermediates of pentafluorophenylmercury bromide reduction near a mercury electrode”, Mendeleev Commun., 16:4 (2006), 234–237

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