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This article is cited in 7 scientific papers (total in 7 papers)
3-Methylcyclopropene-3-carbonitrile as a new enophile of the Alder-ene reaction
R. V. Ashirova, S. A. Appolonovab, G. A. Shamovc, V. V. Plemenkova a Kazan State Medical University, Kazan, Russian Federation
b FSUE 'Antidope Centre', Moscow, Russian Federation
c Division of Informational Technologies, Kazan Scientific Centre of the Russian Academy of Sciences, Kazan, Russian Federation
Abstract:
By the reactions of 3-methylcyclopropene-3-carbonitrile with methylenecyclohexane, α-methylstyrene and β-pinene products of their cyclopropanation have been obtained, the formation of the latter proceeding by the Alder-ene addition scheme. A DFT study of the reaction mechanism shows that most favourable are exo transition states with syn configuration of the CN group and the ene moiety.
Citation:
R. V. Ashirov, S. A. Appolonova, G. A. Shamov, V. V. Plemenkov, “3-Methylcyclopropene-3-carbonitrile as a new enophile of the Alder-ene reaction”, Mendeleev Commun., 16:5 (2006), 276–278
Linking options:
https://www.mathnet.ru/eng/mendc3622 https://www.mathnet.ru/eng/mendc/v16/i5/p276
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