L. Wang, L. Zhang, L. Gong, “Cobalt(III)-catalyzed synthesis of isoquinolines from oximes and alkynes in deep eutectic solvents”, Mendeleev Commun., 33:2 (2023), 243

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Mendeleev Communications, 2023, Volume 33, Issue 2, Pages 243–245
DOI: https://doi.org/10.1016/j.mencom.2023.02.030 (Mi mendc363)

This article is cited in 5 scientific papers (total in 5 papers)

Communications

Cobalt(III)-catalyzed synthesis of isoquinolines from oximes and alkynes in deep eutectic solvents

L. Wang, L. Zhang, L. Gong

School of Chemical and Pharmaceutical Engineering, Changzhou Vocational Institute of Engineering, Changzhou, P.R. China

Full-text PDF (195 kB) Citations (5) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2023.02.030

Graphic abstract: Cobalt(III)-catalyzed synthesis of isoquinolines from oximes and alkynes in deep eutectic solvents

Abstract: A cobalt-catalyzed redox-neutral [4 + 2] annulation of oximes and alkynes in deep eutectic solvents comprising quaternary ammonium compounds and hydrogen bond donors has been developed, the best system being Me₃N+CH₂CO₂- / HOCH(CF₃)₂. No external oxidizing reagent was required, and only water was generated as the secondary product. The catalytic system can be reused in three consecutive cycles.

Keywords: C−H activation, annulation, oximes, alkynes, cobalt catalysis, isoquinolines.

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Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(1.1 Mb)

Citation: L. Wang, L. Zhang, L. Gong, “Cobalt(III)-catalyzed synthesis of isoquinolines from oximes and alkynes in deep eutectic solvents”, Mendeleev Commun., 33:2 (2023), 243–245

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https://www.mathnet.ru/eng/mendc/v33/i2/p243

This publication is cited in the following 5 articles:

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