M. G. Shaibakova, N. A. Rikhter, L. K. Dil'mukhametova, I. R. Ramazanov, “Cp2TiCl2-catalyzed synthesis of tetraalkyl-substituted pyrazines by the reaction of nitriles with EtAlCl2 and Mg”, Mendeleev Commun., 33:2 (2023), 246

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Mendeleev Communications, 2023, Volume 33, Issue 2, Pages 246–248
DOI: https://doi.org/10.1016/j.mencom.2023.02.031 (Mi mendc364)

This article is cited in 1 scientific paper (total in 1 paper)

Communications

Cp₂TiCl₂-catalyzed synthesis of tetraalkyl-substituted pyrazines by the reaction of nitriles with EtAlCl₂ and Mg

M. G. Shaibakova, N. A. Rikhter, L. K. Dil'mukhametova, I. R. Ramazanov

Institute of Petrochemistry and Catalysis, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation

Full-text PDF (310 kB) Citations (1) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2023.02.031

Graphic abstract: Cp<sub>2</sub>TiCl<sub>2</sub>-catalyzed synthesis of tetraalkyl-substituted pyrazines by the reaction of nitriles with EtAlCl<sub>2</sub> and Mg

Abstract: Tetraalkyl-substituted pyrazines were obtained by the multicomponent reaction of aliphatic linear nitriles with EtAlCl₂ in the presence of Mg and Cp₂TiCl₂ catalyst in 60–91% yields. The same processing of isobutyronitrile gave 2,4,5-triisopropyl-1H-imidazole in 56% yield.

Keywords: metal complex catalysis, dichlorobis(η⁵-cyclopentadienyl)titanium, ethylaluminum dichloride, nitriles, pyrazines, imidazoles.

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Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(1.1 Mb)

Citation: M. G. Shaibakova, N. A. Rikhter, L. K. Dil'mukhametova, I. R. Ramazanov, “Cp₂TiCl₂-catalyzed synthesis of tetraalkyl-substituted pyrazines by the reaction of nitriles with EtAlCl₂ and Mg”, Mendeleev Commun., 33:2 (2023), 246–248

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https://www.mathnet.ru/eng/mendc/v33/i2/p246

This publication is cited in the following 1 articles:

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