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This article is cited in 3 scientific papers (total in 3 papers)
Macrocyclic binuclear copper(II) and nickel(II) complexes: the key role of central ions in hydrogen peroxide electrocatalysis
N. V. Roznyatovskaya, G. A. Tsirlina, V. V. Roznyatovskii, A. S. Mitiaev, Y. D. Smurnyy
Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
Abstract:
The electrochemistry of the macrocyclic dicopper(II) and dinickel(II) complexes [M2L]Cl2, where L is the [2+2] condensation product of 1,3-diaminopropane and 2,6-diformyl-4-tert-butylphenol, is reported in relation to hydrogen peroxide electrocatalysis on mercury. The opposite effects observed with [Cu2L]Cl2 (inhibition) and [Ni2L]Cl2 (enhancement) are explained by different reduction mechanisms.
Citation:
N. V. Roznyatovskaya, G. A. Tsirlina, V. V. Roznyatovskii, A. S. Mitiaev, Y. D. Smurnyy, “Macrocyclic binuclear copper(II) and nickel(II) complexes: the key role of central ions in hydrogen peroxide electrocatalysis”, Mendeleev Commun., 15:3 (2005), 93–95
Linking options:
https://www.mathnet.ru/eng/mendc3692 https://www.mathnet.ru/eng/mendc/v15/i3/p93
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