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This article is cited in 2 scientific papers (total in 2 papers)
Regioselective chlorination of 4- and 5-methyl-2,2,2-trichlorobenzo[d]-1,3,2-dioxaphospholes
E. N. Varaksina, V. F. Mironov, A. A. Shtyrlina, A. B. Dobrynin, I. A. Litvinov, A. I. Konovalov
A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation
Abstract:
The reactions of 4- and 5-methyl-2,2,2-trichlorobenzo[d]-1,3,2-dioxaphospholes with molecular chlorine in an 1:1 ratio occur selectively to give 4-methyl-2,2,2,5-tetrachloro- and 5-methyl-2,2,2,6-tetrachlorobenzo[d]-1,3,2-dioxaphospholes, which undergo hydrolysis to 4-chloro-3-methyl- and 4-chloro-5-methyl-1,2-dihydroxybenzenes, respectively.
Citation:
E. N. Varaksina, V. F. Mironov, A. A. Shtyrlina, A. B. Dobrynin, I. A. Litvinov, A. I. Konovalov, “Regioselective chlorination of 4- and 5-methyl-2,2,2-trichlorobenzo[d]-1,3,2-dioxaphospholes”, Mendeleev Commun., 15:3 (2005), 103–105
Linking options:
https://www.mathnet.ru/eng/mendc3698 https://www.mathnet.ru/eng/mendc/v15/i3/p103
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