|
This article is cited in 8 scientific papers (total in 8 papers)
Acyl C→N migration in the thioureidomethylation of 2-(4-methylbenzoyl)cyclohexanone
A. D. Shutaleva, N. E. Zhukhlistovab, G. V. Gurskayac
a M.V. Lomonosov Institute of Fine Chemical Technologies, MIREA - Russian Technological University, Moscow, Russian Federation
b A.V. Shubnikov Institute of Crystallography, FSRC ‘Crystallography and Photonics', Russian Academy of Sciences, Moscow, Russian Federaion
c V.A. Engelhardt Institute of Molecular Biology, Russian Academy of Sciences, Moscow, Russian Federation
Abstract:
The thioureidomethylation of the sodium enolate of 2-(4-methylbenzoyl)cyclohexanone 3 with N-(tosylmethyl)thiourea 1a or N-(azidomethyl)thiourea 2 in acetonitrile results in the unexpected formation of N-(4-methylbenzoyl)-N’-[(2-oxocyclohexyl)-methyl]thiourea 6, which was structurally characterised by X-ray diffraction analysis.
Citation:
A. D. Shutalev, N. E. Zhukhlistova, G. V. Gurskaya, “Acyl C→N migration in the thioureidomethylation of 2-(4-methylbenzoyl)cyclohexanone”, Mendeleev Commun., 14:1 (2004), 31–33
Linking options:
https://www.mathnet.ru/eng/mendc3793 https://www.mathnet.ru/eng/mendc/v14/i1/p31
|
|
Contact us: