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This article is cited in 15 scientific papers (total in 15 papers)
Efficient resolution of the cis-[Ru(phen)2(MeCN)2]2+ complex (phen = 1,10-phenanthroline) using Δ-[tris(tetrachlorobenzenediolato)-phosphate(V)] as a chiral counter-ion
M. Grusellea, R. Thouvenota, R. Caspara, K. Boubekeura, H. Amouria, M. Ivanovb, K. Tõnsuaaduc a Laboratoire de Chimie Inorganique et Matériaux Moléculaires, CNRS, Université Pierre et Marie Curie, Paris, France
b Department of Chemistry, Russian State Pedagogical University, St. Petersburg, Russian Federation
c Institute of Chemical Engineering, Tallinn Technical University, Tallinn, Estonia
Abstract:
The synthesis of cis-Ru(phen)2(MeCN)2][(Δ)-tris(tetrachlorobenzenediolato)phosphate(V)]2 abbreviated as [1]-[Δ-TRISPHAT]2 and the separation of a mixture of the diastereomeric ion pairs by column chromatography are considered. The X-ray structure of [Δ-1][Δ-TRISPHAT]2 is briefly described, as well as the CD curves of [Δ-1][Δ-TRISPHAT]2 and [Δ-1][Δ-TRISPHAT]2 fractions.
Citation:
M. Gruselle, R. Thouvenot, R. Caspar, K. Boubekeur, H. Amouri, M. Ivanov, K. Tõnsuaadu, “Efficient resolution of the cis-[Ru(phen)2(MeCN)2]2+ complex (phen = 1,10-phenanthroline) using Δ-[tris(tetrachlorobenzenediolato)-phosphate(V)] as a chiral counter-ion”, Mendeleev Commun., 14:6 (2004), 282–283
Linking options:
https://www.mathnet.ru/eng/mendc3911 https://www.mathnet.ru/eng/mendc/v14/i6/p282
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