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Mendeleev Communications, 2004, Volume 14, Issue 6, Pages 287–290
DOI: https://doi.org/10.1070/MC2004v014n06ABEH002003
(Mi mendc3914)
 

This article is cited in 4 scientific papers (total in 4 papers)

Enantiodivergent total synthesis of trioxilins B3 using Sharpless asymmetric olefin dihydroxylation

M. A. Lapitskaya, L. L. Vasiljeva, P. M. Demin, K. K. Pivnitsky

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
Full-text PDF (258 kB) Citations (4)
Abstract: The unknown 11,12-threo-stereoisomers of B-type trioxilins, (10R, 11R, 12S)-TrXB3, its (10S)-epimer and their enantiomers were synthesized (as methyl esters) from a common racemic precursor, viz., methyl rac-10-hydroxyeicos-11(E)-ene-5,8,14-triynoate, by Sharpless enantiodirected dihydroxylation of the double bond as the key step.
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Document Type: Article
Language: English


Citation: M. A. Lapitskaya, L. L. Vasiljeva, P. M. Demin, K. K. Pivnitsky, “Enantiodivergent total synthesis of trioxilins B3 using Sharpless asymmetric olefin dihydroxylation”, Mendeleev Commun., 14:6 (2004), 287–290
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  • https://www.mathnet.ru/eng/mendc/v14/i6/p287
  • This publication is cited in the following 4 articles:
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