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Mendeleev Communications, 2004, Volume 14, Issue 6, Pages 297–299
DOI: https://doi.org/10.1070/MC2004v014n06ABEH002012 (Mi mendc3918) 		 
This article is cited in 1 scientific paper (total in 1 paper)

The photochemistry of optically active (E)-cyclooctene: lamp versus laser

F. Gaoa, R.-h. Lib, R. N. Comptonab, R. M. Pagnia

a Department of Chemistry, University of Tennessee, Knoxville, USA
b Department of Physics, University of Tennessee, Knoxville, USA
Full-text PDF (214 kB) Citations (1)
DOI: https://doi.org/10.1070/MC2004v014n06ABEH002012
Abstract: The photochemistry of optically active (E)-cyclooctene in cyclopentane was initiated with a lamp at ca. 254 nm and a Nd-YAG laser at 266 nm. The alkene racemizes slightly faster than it isomerizes to (Z)-cyclooctene, suggesting a previously hidden mechanism of E–Z photointerconversion. The photoreaction at 266 nm may be multiphoton in character.
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Document Type: Article
Language: English


Citation: F. Gao, R.-h. Li, R. N. Compton, R. M. Pagni, “The photochemistry of optically active (E)-cyclooctene: lamp versus laser”, Mendeleev Commun., 14:6 (2004), 297–299
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  • https://www.mathnet.ru/eng/mendc/v14/i6/p297
    • This publication is cited in the following 1 articles:
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