S. V. Chapyshev, “Effect of spin density on the photochemical stability of aromatic nitrenes”, Mendeleev Commun., 13:2 (2003), 53

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Mendeleev Communications, 2003, Volume 13, Issue 2, Pages 53–55
DOI: https://doi.org/10.1070/MC2003v013n02ABEH001722 (Mi mendc3953)

This article is cited in 22 scientific papers (total in 22 papers)

Effect of spin density on the photochemical stability of aromatic nitrenes

S. V. Chapyshev

Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation

Full-text PDF (139 kB) Citations (22)

DOI: https://doi.org/10.1070/MC2003v013n02ABEH001722

Abstract: FTIR studies and UB3LYP/6-31G* calculations showed that triplet nitreno-1,3,5-triazines with zero-field splitting D-parameters of |D/hc| > 1.40 cm^–1 and spin populations on the nitrene centres of ρ_N > 1.77 are photochemically very stable and do not rearrange into ring-expanded products on photolysis in cryogenic matrices.

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Document Type: Article

Language: English

Citation: S. V. Chapyshev, “Effect of spin density on the photochemical stability of aromatic nitrenes”, Mendeleev Commun., 13:2 (2003), 53–55

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This publication is cited in the following 22 articles:

Citing articles in Google Scholar: Russian citations, English citations
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