S. S. Lunkov, A. A. Zemtsov, V. V. Levin, A. D. Dilman, “Photocatalytic reduction of fluoroalkyl-substituted alcohols activated by pentafluoropyridine”, Mendeleev Commun., 33:3 (2023), 387

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Mendeleev Communications, 2023, Volume 33, Issue 3, Pages 387–389
DOI: https://doi.org/10.1016/j.mencom.2023.04.028 (Mi mendc405)

This article is cited in 6 scientific papers (total in 6 papers)

Communications

Photocatalytic reduction of fluoroalkyl-substituted alcohols activated by pentafluoropyridine

S. S. Lunkov^ab, A. A. Zemtsov^a, V. V. Levin^a, A. D. Dilman^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Full-text PDF (221 kB) Citations (6) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2023.04.028

Graphic abstract: Photocatalytic reduction of fluoroalkyl-substituted alcohols activated by pentafluoropyridine

Abstract: A new method for deoxygenation of fluoroalkyl-substituted alcohols involves derivatization of the hydroxy group with pentafluoropyridine followed by photoredox catalyzed reduction of the obtained hetaryl ethers using γ-terpinene as a source of hydrogen. The initial alcohols can be easily obtained by nucleophilic fluoroalkylation of the corresponding aldehydes.

Keywords: photocatalysis, radicals, deoxygenation, organofluorine compounds, alcohols, ethers.

Bibliographic databases:

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(6.9 Mb)

Citation: S. S. Lunkov, A. A. Zemtsov, V. V. Levin, A. D. Dilman, “Photocatalytic reduction of fluoroalkyl-substituted alcohols activated by pentafluoropyridine”, Mendeleev Commun., 33:3 (2023), 387–389

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https://www.mathnet.ru/eng/mendc405

https://www.mathnet.ru/eng/mendc/v33/i3/p387

This publication is cited in the following 6 articles:

Citing articles in Google Scholar: Russian citations, English citations
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