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This article is cited in 65 scientific papers (total in 65 papers)
Preparation of 1,2-bis(3,4-dicyanophenoxymethyl)benzene and the binuclear zinc phthalocyanine derived from it
A. Yu. Tolbina, A. V. Ivanovb, L. G. Tomilovaa, N. S. Zefirovb a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
b Institute of Physiologically Active Compounds, Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
Abstract:
A method of synthesis of 1,2-bis(3,4-dicyanophenoxymethyl)benzene from the 1,2-bis(hydroxymethyl)benzene and 4-nitrophthalodinitrile is developed. Its tetramerization with Zn(OAc)2·2H2O gives a binuclear zinc phthalocyanine of a new type, containing four o-phenylidene bridges. The use of microwave heating decreases reaction time and increases yield.
Citation:
A. Yu. Tolbin, A. V. Ivanov, L. G. Tomilova, N. S. Zefirov, “Preparation of 1,2-bis(3,4-dicyanophenoxymethyl)benzene and the binuclear zinc phthalocyanine derived from it”, Mendeleev Commun., 12:3 (2002), 96–97
Linking options:
https://www.mathnet.ru/eng/mendc4110 https://www.mathnet.ru/eng/mendc/v12/i3/p96
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