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Mendeleev Communications, 2002, Volume 12, Issue 4, Pages 137–140
DOI: https://doi.org/10.1070/MC2002v012n04ABEH001612
(Mi mendc4131)
 

This article is cited in 18 scientific papers (total in 18 papers)

Chiral 1-alkoxyaziridines: resolution, nitrogen inversion, stucture and diastereomeric transformations

R. G. Kostyanovskya, V. Schurigb, O. Trappb, K. A. Lyssenkoc, B. B. Averkievc, G. K. Kadorkinaa, A. V. Prosyanikd, V. R. Kostyanovskya

a N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
b Institut fuer Organische Chemie, Eberhard Karls Universitaet Tuebingen, Tuebingen, Germany
c A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
d Ukrainian State University of Chemical Technology, Dnepropetrovsk, Ukraine
Abstract: The resolution of enantiomers by chiral chromatography and the determination of nitrogen inversion activation parameters by dynamic chromatography have been carried out for aziridines 1–3; the structures of aziridines 4–7 have been studied; the complete diastereomeric transformation of (S,R)-(+)-8a into (R,R)-(–)-8b has been performed, and the conglomerate of high-melting diastereomer (±)-9 has been found.
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Document Type: Article
Language: English


Citation: R. G. Kostyanovsky, V. Schurig, O. Trapp, K. A. Lyssenko, B. B. Averkiev, G. K. Kadorkina, A. V. Prosyanik, V. R. Kostyanovsky, “Chiral 1-alkoxyaziridines: resolution, nitrogen inversion, stucture and diastereomeric transformations”, Mendeleev Commun., 12:4 (2002), 137–140
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  • https://www.mathnet.ru/eng/mendc/v12/i4/p137
  • This publication is cited in the following 18 articles:
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