V. V. Pelipko, R. I. Baichurin, K. A. Lyssenko, E. V. Kondrashov, S. V. Makarenko, “New spiro-fused 2-nitrocyclopropanecarboxylates: Synthesis and structure”, Mendeleev Commun., 33:4 (2023), 451

Mendeleev Communications

RUS ENG

JOURNALS PEOPLE ORGANISATIONS CONFERENCES SEMINARS VIDEO LIBRARY PACKAGE AMSBIB

JavaScript is disabled in your browser. Please switch it on to enable full functionality of the website

	General information
	Latest issue
	Archive

	Search papers
	Search references

	RSS
	Latest issue
	Current issues
	Archive issues
	What is RSS

Mendeleev Commun.:
Year:
Volume:
Issue:
Page:
	Find

Personal entry:
Login:
Password:
	Save password
	Enter
	Forgotten password?
	Register

Mendeleev Communications, 2023, Volume 33, Issue 4, Pages 451–454
DOI: https://doi.org/10.1016/j.mencom.2023.06.003 (Mi mendc424)

This article is cited in 4 scientific papers (total in 4 papers)

Communications

New spiro-fused 2-nitrocyclopropanecarboxylates: Synthesis and structure

V. V. Pelipko^a, R. I. Baichurin^a, K. A. Lyssenko^bc, E. V. Kondrashov^d, S. V. Makarenko^a

^a Herzen State Pedagogical University of Russia, St. Petersburg, Russian Federation
^b G.V. Plekhanov Russian University of Economics, Moscow, Russian Federation
^c Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^d A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation

Full-text PDF (362 kB) Citations (4) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2023.06.003

Graphic abstract: New spiro-fused 2-nitrocyclopropanecarboxylates: Synthesis and structure

Abstract: Reactions of alkyl 3-bromo-3-nitroacrylates with cyclic CH-acids, Meldrum’s acid or 3-methyl-1-phenylpyrazol-5-one, afford new spiro-fused 2-nitrocyclopropanecarboxylates. In the case of Meldrum’s acid, the products are formed as individual diastereomers. The obtained experimental results are confirmed by quantum chemical calculations (B3LYP/6-311+G(d,p) taking into account solvent effects).

Keywords: 1-halo-1-nitroethenes, 3-bromo-3-nitroacrylates, Meldrum’s acid, 3-methyl-1-phenylpyrazol-5-one, nitrocyclopropane, spirocyclopropane.

Bibliographic databases:

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(3.2 Mb)

Citation: V. V. Pelipko, R. I. Baichurin, K. A. Lyssenko, E. V. Kondrashov, S. V. Makarenko, “New spiro-fused 2-nitrocyclopropanecarboxylates: Synthesis and structure”, Mendeleev Commun., 33:4 (2023), 451–454

Linking options:

https://www.mathnet.ru/eng/mendc424

https://www.mathnet.ru/eng/mendc/v33/i4/p451

This publication is cited in the following 4 articles:

Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

Registration to the website

Logotypes