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This article is cited in 5 scientific papers (total in 5 papers)
An unusual Bamford–Stevens reaction of 17-toluenesulfonylhydrazono-3β-acetoxy-14α-hydroxyandrost-5-ene
V. V. Khripacha, V. N. Zhabinskiia, A. I. Kotyatkinaa, G. P. Fandoa, A. S. Lyakhova, A. A. Govorovaa, J. van der Louwb, M. B. Groenb, A. de Grootc a Institute of Bioorganic Chemistry, National Academy of Sciences of Belarus, Minsk, Belarus
b Department of Medicinal Chemistry, N.V. Organon, Oss, The Netherlands
c Laboratory of Organic Chemistry and Research Centre, Wageningen Agricaltural University, Wageningen, The Netherlands
Abstract:
The Bamford–Stevens reaction of 17-toluenesulfonylhydrazono-3β-acetoxy-14α-hydroxyandrost-5-ene was found to proceed with migration of the 18-methyl group and formation of a 13,14-epoxide.
Citation:
V. V. Khripach, V. N. Zhabinskii, A. I. Kotyatkina, G. P. Fando, A. S. Lyakhov, A. A. Govorova, J. van der Louw, M. B. Groen, A. de Groot, “An unusual Bamford–Stevens reaction of 17-toluenesulfonylhydrazono-3β-acetoxy-14α-hydroxyandrost-5-ene”, Mendeleev Commun., 11:4 (2001), 144–145
Linking options:
https://www.mathnet.ru/eng/mendc4262 https://www.mathnet.ru/eng/mendc/v11/i4/p144
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