A. V. Budkova, V. G. Merkulov, R. E. Ivanov, M. N. Zharkov, I. V. Kuchurov, S. G. Zlotin, “Application of NO2/supercritical CO2 system for safe and selective nitration of adamantanes and tertiary alkyl bromides”, Mendeleev Commun., 33:4 (2023), 461

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Mendeleev Communications, 2023, Volume 33, Issue 4, Pages 461–462
DOI: https://doi.org/10.1016/j.mencom.2023.06.006 (Mi mendc427)

This article is cited in 7 scientific papers (total in 7 papers)

Communications

Application of NO₂/supercritical CO₂ system for safe and selective nitration of adamantanes and tertiary alkyl bromides

A. V. Budkova^ab, V. G. Merkulov^ab, R. E. Ivanov^a, M. N. Zharkov^a, I. V. Kuchurov^a, S. G. Zlotin^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation

Full-text PDF (224 kB) Citations (7) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2023.06.006

Graphic abstract: Application of NO<sub>2</sub>/supercritical CO<sub>2</sub> system for safe and selective nitration of adamantanes and tertiary alkyl bromides

Abstract: A concise safe approach for selective nitration and nitroxylation of tert-alkanes, in particular adamantane, and tert-alkyl bromides utilizing NO₂ in supercritical CO₂ medium has been established. Major reaction products were tert-alkyl nitro compounds and tert-alkyl nitrates depending on the reaction conditions.

Keywords: nitroalkanes, nitrates, nitrogen dioxide, supercritical carbon dioxide, adamantane, tert-alkyl bromides.

Bibliographic databases:

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(1.4 Mb)

Citation: A. V. Budkova, V. G. Merkulov, R. E. Ivanov, M. N. Zharkov, I. V. Kuchurov, S. G. Zlotin, “Application of NO₂/supercritical CO₂ system for safe and selective nitration of adamantanes and tertiary alkyl bromides”, Mendeleev Commun., 33:4 (2023), 461–462

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https://www.mathnet.ru/eng/mendc/v33/i4/p461

This publication is cited in the following 7 articles:

Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

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