V. E. Shambalova, R. V. Larkovich, S. A. Ponomarev, A. S. Aldoshin, K. A. Lyssenko, V. G. Nenajdenko, “Stereoselective epoxidation of 4-fluoro-4-nitrocyclohexenes”, Mendeleev Commun., 33:4 (2023), 463

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Mendeleev Communications, 2023, Volume 33, Issue 4, Pages 463–465
DOI: https://doi.org/10.1016/j.mencom.2023.06.007 (Mi mendc428)

This article is cited in 3 scientific papers (total in 3 papers)

Communications

Stereoselective epoxidation of 4-fluoro-4-nitrocyclohexenes

V. E. Shambalova, R. V. Larkovich, S. A. Ponomarev, A. S. Aldoshin, K. A. Lyssenko, V. G. Nenajdenko

Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Full-text PDF (389 kB) Citations (3) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2023.06.007

Graphic abstract: Stereoselective epoxidation of 4-fluoro-4-nitrocyclohexenes

Abstract: Novel fluorinated α-epoxycyclohexanes were synthesized in up to 96% yields by epoxidation of the Diels–Alder adducts of β-fluoro-β-nitrostyrenes and 2,3-dimethylbuta-1,3-diene. The epoxidation with m-chloroperoxybenzoic acid and subsequent hydrolysis into diols were found to proceed in a highly stereoselective manner.

Keywords: organofluorine compounds, nitrostyrenes, Diels–Alder reaction, epoxidation, ring-opening, hydrolysis, diols.

Bibliographic databases:

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(6.6 Mb)

Citation: V. E. Shambalova, R. V. Larkovich, S. A. Ponomarev, A. S. Aldoshin, K. A. Lyssenko, V. G. Nenajdenko, “Stereoselective epoxidation of 4-fluoro-4-nitrocyclohexenes”, Mendeleev Commun., 33:4 (2023), 463–465

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https://www.mathnet.ru/eng/mendc428

https://www.mathnet.ru/eng/mendc/v33/i4/p463

This publication is cited in the following 3 articles:

Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

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