Abstract:
A new cubane cluster [Cu4I4(AsAn3)4] was synthesized in 82% yield by the reaction of tris(p-anisyl)arsine (AsAn3) with CuI. At ambient temperature, this cluster exhibits bright yellow-green phosphorescence (λmax = 546 nm) with the quantum yield of 35% and 4.1 μs decay time.
Citation:
Ya. V. Demyanov, M. I. Rakhmanova, I. Yu. Bagryanskaya, A. V. Artem'ev, “Cu4I4-cubane cluster based on tris(p-anisyl)arsine: Synthesis, crystal structure and photophysical properties”, Mendeleev Commun., 33:4 (2023), 484–486
Linking options:
https://www.mathnet.ru/eng/mendc435
https://www.mathnet.ru/eng/mendc/v33/i4/p484
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