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This article is cited in 16 scientific papers (total in 16 papers)
Formation of stable 1,2,3-benzodithiazolyl radicals by thermolysis of 1,3,2,4-benzodithiadiazines
V. A. Bagryanskya, I. V. Vlasyukb, Yu. V. Gatilovc, A. Yu. Makarovc, Yu. N. Molina, V. V. Shcherbukhind, A. V. Zibarevc
a V.V. Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
b Department of Natural Sciences, Novosibirsk State University, Novosibirsk, Russian Federation
c N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
d N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
Abstract:
Mild thermolysis (at 110–150 °C) of 1,3,2,4-benzodithiadiazine 1 and its derivatives 2–6 in hydrocarbon solvents quantitatively yielded stable 1,2,3-benzodithiazolyl π-radicals via a first-order reaction (Ea = 76.2 kJ mol–1, k0 = 4.34×105 s–1 for 1).
Citation:
V. A. Bagryansky, I. V. Vlasyuk, Yu. V. Gatilov, A. Yu. Makarov, Yu. N. Molin, V. V. Shcherbukhin, A. V. Zibarev, “Formation of stable 1,2,3-benzodithiazolyl radicals by thermolysis of 1,3,2,4-benzodithiadiazines”, Mendeleev Commun., 10:1 (2000), 5–7
Linking options:
https://www.mathnet.ru/eng/mendc4354 https://www.mathnet.ru/eng/mendc/v10/i1/p5
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