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This article is cited in 2 scientific papers (total in 2 papers)
Tunnelling effects in the oxidative addition of a dihydrogen molecule to the palladium ethylenediphosphine complexes [H2P(CH2)2PH2]Pd and [H2P(CH2)2PH2]Pd2
V. M. Mamaeva, I. P. Gloriozova, V. V. Simonyana, E. V. Zernovaa, E. M. Myshakina, Yu. V. Babinb a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
b Far Eastern State Academy of Economics and Management, Vladivostok, Russian Federation
Abstract:
In terms of the reaction-path Hamiltonian formalism, the ligand environment has been found to have almost no effect on the activation barrier in the oxidative addition of H2 to the title complexes (the under-barrier tunnelling in the reaction was predominant at T < 230 K).
Citation:
V. M. Mamaev, I. P. Gloriozov, V. V. Simonyan, E. V. Zernova, E. M. Myshakin, Yu. V. Babin, “Tunnelling effects in the oxidative addition of a dihydrogen molecule to the palladium ethylenediphosphine complexes [H2P(CH2)2PH2]Pd and [H2P(CH2)2PH2]Pd2”, Mendeleev Commun., 10:1 (2000), 12–14
Linking options:
https://www.mathnet.ru/eng/mendc4357 https://www.mathnet.ru/eng/mendc/v10/i1/p12
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