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This article is cited in 2 scientific papers (total in 2 papers)
Unexpected isomerization in the series of fluorine-containing 2,3-dihydro-1H-1,4-diazepines with a 2-aminoethyl group at one of the nitrogen atoms
V. Ya. Sosnovskikha, I. I. Vorontsovb, V. A. Kutsenkoa, Yu. G. Yatluka a Department of Chemistry, Ural Federal University, Ekaterinburg, Russian Federation
b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
Abstract:
Under kinetic control conditions, 6-methoxy-2-(1,1,2,2-tetrafluoroethyl)chromone reacts with diethylenetriamine to form 5-(2-hydroxy-5-methoxyphenyl)-7-(1,1,2,2-tetrafluoroethyl)-1,4,8-triazabicyclo[5.3.0]dec-4-ene, and the latter undergoes isomerization to the title compound, which is more thermodynamically stable.
Citation:
V. Ya. Sosnovskikh, I. I. Vorontsov, V. A. Kutsenko, Yu. G. Yatluk, “Unexpected isomerization in the series of fluorine-containing 2,3-dihydro-1H-1,4-diazepines with a 2-aminoethyl group at one of the nitrogen atoms”, Mendeleev Commun., 10:2 (2000), 56–58
Linking options:
https://www.mathnet.ru/eng/mendc4379 https://www.mathnet.ru/eng/mendc/v10/i2/p56
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