I. V. Lavrentev, K. E. Shepelenko, I. G. Gnatiuk, A. A. Aleksandrov, Y. Zhang, V. M. Chernyshev, “CH-alkylation of furan derivatives under photoinduced Pd catalysis”, Mendeleev Commun., 33:4 (2023), 494

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Mendeleev Communications, 2023, Volume 33, Issue 4, Pages 494–496
DOI: https://doi.org/10.1016/j.mencom.2023.06.017 (Mi mendc438)

This article is cited in 6 scientific papers (total in 6 papers)

Communications

CH-alkylation of furan derivatives under photoinduced Pd catalysis

I. V. Lavrentev^a, K. E. Shepelenko^a, I. G. Gnatiuk^a, A. A. Aleksandrov^a, Y. Zhang^b, V. M. Chernyshev^a

^a Platov South-Russian State Polytechnic University, Novocherkassk, Russian Federation
^b Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou, China

Full-text PDF (163 kB) Citations (6) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2023.06.017

Graphic abstract: CH-alkylation of furan derivatives under photoinduced Pd catalysis

Abstract: A new method for selective C(5)–H alkylation of 2-substituted furans with tertiary and secondary alkyl bromides under photoinduced by visible light (∼460 nm) palladium catalysis has been developed. The method is relied on the use of available Pd(PPh₃)₄ catalyst under mild conditions (30 ± 5 °C, K₂CO₃ as base), tolerates to various functional groups in furanic substrates and provides from good to excellent yields of alkylated products.

Keywords: furan, CH-alkylation, palladium, photoinduced metal catalysis, 2-hetarylfurans.

Bibliographic databases:

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(4.3 Mb)

Citation: I. V. Lavrentev, K. E. Shepelenko, I. G. Gnatiuk, A. A. Aleksandrov, Y. Zhang, V. M. Chernyshev, “CH-alkylation of furan derivatives under photoinduced Pd catalysis”, Mendeleev Commun., 33:4 (2023), 494–496

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https://www.mathnet.ru/eng/mendc/v33/i4/p494

This publication is cited in the following 6 articles:

Citing articles in Google Scholar: Russian citations, English citations
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