N. F. Lazareva, M. A. Alekseev, I. V. Sterkhova, T. V. Rybalova, “N-Isopropyl-N',N'-diphenyl-N-(silylmethyl)ureas: Synthesis and structure”, Mendeleev Commun., 33:4 (2023), 500

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Mendeleev Communications, 2023, Volume 33, Issue 4, Pages 500–502
DOI: https://doi.org/10.1016/j.mencom.2023.06.019 (Mi mendc440)

This article is cited in 3 scientific papers (total in 3 papers)

Communications

N-Isopropyl-N',N'-diphenyl-N-(silylmethyl)ureas: Synthesis and structure

N. F. Lazareva^a, M. A. Alekseev^a, I. V. Sterkhova^a, T. V. Rybalova^b

^a A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation
^b N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Full-text PDF (379 kB) Citations (3) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2023.06.019

Graphic abstract: <i>N</i>-Isopropyl-<i>N'</i>,<i>N'</i>-diphenyl-<i>N</i>-(silylmethyl)ureas: Synthesis and structure

Abstract: New N-isopropyl-N',N'-diphenyl-N-(silylmethyl)ureas were obtained, and their structure was explored by ¹H, ¹³C, ²⁹Si NMR spectroscopy and X-ray analysis. These results have shown that N-isopropyl-N', N'-diphenyl-N-[(fluorosilyl)-methyl]ureas exist as (O–Si) chelates with intramolecular dative bond C=O→Si.

Keywords: N',N'-diphenyl-N-(silylmethyl)ureas, (O–Si) chelates, dative bond, pentacoordinate silicon atom, organosilicon compounds, NMR, X-ray.

Bibliographic databases:

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(1.7 Mb)

Citation: N. F. Lazareva, M. A. Alekseev, I. V. Sterkhova, T. V. Rybalova, “N-Isopropyl-N',N'-diphenyl-N-(silylmethyl)ureas: Synthesis and structure”, Mendeleev Commun., 33:4 (2023), 500–502

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https://www.mathnet.ru/eng/mendc440

https://www.mathnet.ru/eng/mendc/v33/i4/p500

This publication is cited in the following 3 articles:

Citing articles in Google Scholar: Russian citations, English citations
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