L. Ya. Zakharova, F. G. Valeeva, L. A. Kudryavtseva, A. I. Konovalov, “The kinetics of solvolysis of p-nitrophenyl bis(chloromethyl)phosphinate in a micellar solution of sodium dodecyl sulfate in ethylene glycol: catalysis by metal ions”, Mendeleev Commun., 10:6 (2000), 241

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Mendeleev Communications, 2000, Volume 10, Issue 6, Pages 241–243
DOI: https://doi.org/10.1070/MC2000v010n06ABEH001337 (Mi mendc4480)

This article is cited in 7 scientific papers (total in 7 papers)

The kinetics of solvolysis of p-nitrophenyl bis(chloromethyl)phosphinate in a micellar solution of sodium dodecyl sulfate in ethylene glycol: catalysis by metal ions

L. Ya. Zakharova^a, F. G. Valeeva^a, L. A. Kudryavtseva^a, A. I. Konovalov^b

^a A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation
^b Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russian Federation

Full-text PDF (91 kB) Citations (7)

DOI: https://doi.org/10.1070/MC2000v010n06ABEH001337

Abstract: A 30-fold acceleration of the title reaction due to an increase in the activation entropy and activation enthalpy in the micellar pseudophase compared to ethylene glycol was found; Mg²⁺, Zn²⁺ and La³⁺ ions accelerate the solvolysis by factors of 5, 8 and 20, respectively.

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Document Type: Article

Language: English

Citation: L. Ya. Zakharova, F. G. Valeeva, L. A. Kudryavtseva, A. I. Konovalov, “The kinetics of solvolysis of p-nitrophenyl bis(chloromethyl)phosphinate in a micellar solution of sodium dodecyl sulfate in ethylene glycol: catalysis by metal ions”, Mendeleev Commun., 10:6 (2000), 241–243

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https://www.mathnet.ru/eng/mendc/v10/i6/p241

This publication is cited in the following 7 articles:

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